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The University of Tokyo Takayuki KAWASHIMA "Synthesis, Structure, and Thermolysis of a Pentacoordinate 1,2-Oxastibetane"
Y. Uchiyama, N. Kano, and T. Kawashima, J. Am. Chem. Soc., 125, 13346-13347 (2003).

"Synthesis, Crystal Structure, and Photoreaction of a Disiloxane Bearing Two 2-(Phenylazo)phenyl Groups"
N. Kano, M. Yamamura, F. Komatsu, and T. Kawashima, J. Organomet. Chem., 686, 192-197 (2003)
Koichi Narasaka Preparation of Furans by Palladium-Catalyzed Reaction of Acylchromates and Propargylic Tosylates. M. Nakamura, M. Yamane, H. Sakurai, and K. Narasaka, Heterocycles, Vol. 59, No.1, 333-345, 2003.

Intramolecular Substitution Reacton of Alkylidene-Lithium Carbeniods: Regioselective Synthesis of Indenes. H. Yanagisawa, K. Miura, K. Narasaka, and K. Ando, Helvetica Chimica Acta, Vol.85, 3130-3135, 2002.
Eiichi Nakamura Ball-and-Socket Stacking of Supercharged Geodesic Polyarenes: Bonding by Interstitial Lithium Ions. I. Aprahamian, D. Eisenberg, R. E. Hoffman, T. Sternfeld, Y. Matsuo E. A. Jackson, E. Nakamura, L. T. Scott, T. Sheradsky, and M. Rabinovitz J. Am. Chem. Soc., 127, 9581-9587 (2005).

Regioselective Oxygenative Tetraamination of [60]Fullerene. Fullerene-mediated Reduction of Molecular Oxygen by Amine via Ground State Single Electron Transfer in Dimethyl Sulfoxide, H. Isobe, T. Tanaka, W. Nakanishi, L. Lemiėgre, and E. Nakamura, J. Org. Chem., 70, 4826-4832 (2005).
Tachibana Lab Progress toward the Total Synthesis of Ciguatoxins: A Convergent Synthesis of the FGHIJKLM Ring Fragment,Org. Lett.2002, 4, 2771.

Total Synthesis of (-)-Gambierol,J. Am. Chem. Soc.2002, 124,14893.
Kyoto University Tamio Hayashi Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Coumarins: Asymmetric Synthesis of (R)-Tolterodine.
Chen, Gang; Tokunaga, Norihito; Hayashi, Tamio. Organic Letters 2005, 7(11), 2285-2288.

C2-Symmetric bicyclo[3.3.1]nona-2,6-diene and bicyclo[3.3.2]deca-2,6-diene: new chiral diene ligands based on the 1,5-cyclooctadiene framework.
Otomaru, Yusuke; Kina, Asato; Shintani, Ryo; Hayashi, Tamio. Tetrahedron: Asymmetry  2005, 16(9), 1673-1679.
Keiji Maruoka Evaluation of the relationship between the catalyst structure and regio- as well as stereoselectivity in the chiral ammonium bifluoride-catalyzed asymmetric addition of silyl nitronates to α,β-unsaturated aldehydes.     Ooi, Takashi; Morimoto, Kumiko; Doda, Kanae; Maruoka, Keiji. Chemistry Letters  (2004),  33(7), 824-825.

Development of Highly Diastereo- and Enantioselective Direct Asymmetric Aldol Reaction of a Glycinate Schiff Base with Aldehydes Catalyzed by Chiral Quaternary Ammonium Salts.     Ooi, Takashi; Kameda, Minoru; Taniguchi, Mika; Maruoka, Keiji. J. Am. Chem. Soc.   (2004),  126(31),  9685-9694.
Osaka University Hiroaki SASAI Bifunctional Organocatalysts for Enantioselective aza-Morita-Baylis-Hillman Reaction. K. Matsui, S. Takizawa, and H Sasai, J. Am. Chem. Soc. 2005, 127, 3680.

Micelle-derived Polymer Supports for Enantioselective Catalysts. S. Takizawa, M. L. Patil, F. Yonezawa, K. Marubayashi, H. Tanaka, T. Kawai, and H. Sasai, Tetrahedron Lett. 2005, 46, 1193.
Ikuo UEDA  
Tohuko University    

 
   
University of Cambridge Jonathan W Burton Synthesis of Medium Ring Ethers. 5. The Synthesis of (+)-Laurencin J. W. Burton, J. S. Clark, S. Derrer, T. C. Stork, J. G. Bendall, A. B. Holmes, J. Am. Chem. Soc., 1997, 119, 7483.

Synthesis of medium-ring lactones via tandem methylenation/Claisen rearrangement of cyclic carbonates E. A. Anderson, J. E. P. Davidson, J. R. Harrison, P. T. O'Sullivan, J. W. Burton, I. Collins, A. B. Holmes, Tetrahedron, 2002, 58, 1943.

Jonathan Goodman What Is the Smallest Saturated Acyclic Alkane that Cannot Be Made? J. Chem. Inf. Model. 2005, 45, 81-87.

Experimental data checker: better information for organic chemists Org. Biomol. Chem. 2004, 2, 3067-3070.
Finian Leeper Coenzyme Chemistry, J. Chem. Soc., Perkin Trans. 1, 2001, 144-148.

Enzyme Chemistry, Org. Biomolec. Chem. , 2003, 1, 21-23 and 1443-1446.
Steven Ley Total Synthesis of Spongistatin 1: A New Synthetic Strategy Exploiting its Latent Pseudo Symmetry, M. Ball, M.J. Gaunt, D.F. Hook, A.S. Jessiman, S. Kawahara, P. Orsini, A. Scolaro, A.C. Talbot, H.R. Tanner, S. Yamanoi and S.V. Ley, Angew. Chem. Int. Ed., 2005, in press.

Total Synthesis of Antascomicin B, D.E.A. Brittain, C.M. Griffiths-Jones, M.R. Linder, M.D. Smith, C McCusker, J.S. Barlow, R. Akiyama, K. Yasuda and S.V. Ley, Angew. Chem., Int. Ed. , 2005, 44, 2732.
Ian Paterson Total synthesis of (+)-altohyrtin A / spongistatin 1. Angew. Chem. Int. Ed. 2001, 40, 4055.

A practical synthesis of (+)-discodermolide and analogues. J. Am. Chem. Soc. 2001, 123, 9535.
Jeremy Sanders Pseudorotaxanes and rotaxanes, Angew. Chemie Intl. Edn., 2004, 43, 1959; J. Am. Chem. Soc., 2004, 126, 9884

Selection and amplification of hosts and catalysts from dynamic combinatorial libraries of macrocyclic disulfides in water, Science, 2002, 297, 590-593; Angewandte Chemie, 2003, 42, 1270

Jonathan Spencer First evidence that the mechanism of catalytic hydrogenation with homogeneous palladium and rhodium catalysts is strongly influenced by substrate polarity, J. Am. Chem. Soc. 1997, 119, 5257 Stereoselective deoxygenation of myo-Inositol monotosylates with lithium triethylborohydride, J. Org. Chem., 1996, 61, 3234 Biosynthesis of Vitamin B12, J. Am. Chem. Soc. 1996, 118, 1657; 1994, 116, 4991
Stuart Warren A simple, general and efficient ketone synthesis via alkylation and dephosphinoylation of β-keto-diphenylphosphine oxides, Chem. Commun., 2004, 2598-2599.

Identification of 3-(Acylamino)azepan-2-ones as Stable Broad-Spectrum Chemokine Inhibitors Resistant to Metabolism in Vivo, J. Med. Chem., 2005, 48, 867-874.
University of Oxford Jack Baldwin "Contrasting fates for 6-a-methylpenicillin N upon oxidation by DAOCS and DAOC/DACS," CS Hamilton, A Yasuhara, JE Baldwin, MD Lloyd and PJ Rutledge, Bioorg. Med. Chem. Lett. 11, 2511 (2001).

“Studies Towards the Biomimetic Synthesis of the Nonadrides CP-225,917 and CP-263,114” JE Baldwin, RM Adlington, F Roussi, PG Bulger, R Marquez and AVW Mayweg, Tetrahedron 57, 7409 (2001)

Robert M. Adlington “Biomimetic Synthesis of (±)-9,10-Deoxytridachione”, R M Adlington, J E Moses, R Rodriquez, S J Eade and J E Baldwin, J. Chem. Soc. Chem. Commun., in press.

“Biomimetic Total Synthesis of (+)-Himbacine”, R M Adlington, K Tchabanenko, A R Cowley and J E Baldwin , Organic Letts., 2005, 7, 585.
J.M. Brown Imidazo[1,5-a]pyridine: A Versatile Architecture for Stable N-Heterocyclic Carbenes, M. Alcarazo, S. J. Roseblade, A. R. Cowley, R. Fernandez, J. M. Brown, and J. M. Lassaletta, J. Am. Chem. Soc., 2005, 127, 3290-3292.

Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles, E. Capito, J. M. Brown and A. Ricci, Chem. Commun. 2005, 1854-6.
S.G. Davies Preparation of (1R,2S,5S)- and (1S,2R,5R)-methyl 2-amino-5-tert-butyl-cyclopentane-1-carboxylate by Parallel Kinetic Resolution of methyl (±)-5-tert-butyl-cyclopentene-1-carboxylate, S. G. Davies, D. D'ez,  M. M. El Hammouni, N. M. Garrido, A. C. Garner, M. J. C. Long, R. M. Morrison, A. D. Smith, M. J. Sweet and J. M. Withey, Chem. Commun., 2003, 2410

The Asymmetric Synthesis of anti-(2S,3S)- and syn-(2R,3S)-diaminobutanoic acid , M. E. Bunnage, A. J. Burke, S. G. Davies, N. L. Millican, R. L. Nicholson, P. M. Roberts and A. D. Smith, Org. Biomol. Chem., 2003, 3708
B.G. Davis J.P.S. Badyal, A. Cameron, N. Cameron, D. Coe, R. Cox, B.G. Davis,  L. Oates, G. Oye and P.G. Steel, Tetrahedron Lett. 2001

Probing the Breadth of Glycosyltransferases: In Vitro Remodeling of a Polyketide Antibiotic Creates Active Bacterial Uptake and Enhances Potency, J. Am. Chem. Soc. 2005, 127, 9336-9337
T.J. Donohoe A non-carbohydrate based approach to polyhydroxylated pyrrolidizines; total syntheses of the natural products hyacinthacine A1 and 1-epiaustraline, Timothy J. Donohoe*, Herman O. Sintim and Jackie Hollinshead, Journal of Organic Chemistry, 2005

Oxidative cyclisations of diols derived from 1,5-dienes: formation of enantiopure cis-tetrahydrofurans using catalytic osmium tetroxide and a formal synthesis of (+)-cis-solamin, Timothy J. Donohoe and Sam Butterworth, Angewandte Chemie, 2005, 44, 4766-4768.
A.J. Fairbanks Ennis, S. C.; Cumpstey, I.; Fairbanks, A. J.; Butters, T. D.; Mackeen, M.; Wormald, M. R., Total synthesis of the Glc3Man N-glycan tetrasaccharide, Tetrahedron, 2002, 58, 9403-9411.

M. Aloui, D. Chambers, I. Cumpstey, A. J. Fairbanks, A. J. Redgrave, C. M. P. Seward Stereoselective 1,2-cis glycosylation of 2-O-allyl protected thioglycosides, Chem. Eur. J., 2002, 8, 2608-2621.
G.W.J. Fleet R.A. Jockusch, F.O. Talbot, N. Asano, G.W.J. Fleet and  J.P. Simons, Gas phase structure and conformation of the glycosidase and ceramide glucosyltransferase inhibitor N-benzyl-deoxynojirimycin, Phys. Chem. Chem. Phys. 2004, 108, DOI: 10.1039/b413672a.

D. Hotchkiss, R. Soengas, M. Iezzi Simone, J. van Ameijde, S. Hunter, A. R. Cowley andG. W. J. Fleet, Kiliani on ketoses: branched carbohydrate building blocks from D-fructose and L-sorbose, Tetrahedron Lett. 2004, 45, 9461-9464.
V. Gouverneur "Stereoselective synthesis of internal allylic fluorides" S. Thibaudeau, R. Fuller and V. Gouverneur Org. Biomol. Chem. 2004, 2, 8, 1110-1112.

"Unusual reversal of regioselectivity in antibody-mediated aldol additions with unsymmetrical methyl ketones" V. Maggiotti, S. Bahmanyar, M. Reiter, M. Resmini, K. N. Houk and V. Gouverneur Tetrahedron 2004, 60, 3, 619-632.
D.M. Hodgson 'Use of Allene in 1,3-Dipolar Addition to a Carbonyl Ylide: Syntheses of 3-Hydroxy-cis-nemorensic Acid and Nemorensic Acid' D. M. Hodgson and F. Le Strat, Chem. Commun., 2004, 821.

'Enamines from Terminal Epoxides and Hindered Lithium Amides' D. M. Hodgson, C. Bray and N. D. Kindon, J. Am. Chem. Soc., 2004, 126, 6870.
M.G. Moloney  
J. Robertson  
C.J. Schofield "Oligomeric structure of proclavaminic acid amidino hydrolase: evolution of a hydrolytic enzyme in clavulanic acid biosynthesis", Elkins, J. M., Clifton, I. J., Hernandez, H., Doan, L. X., Robinson, C. V., Schofield, C. J., and Hewitson, K. S. (2002) Biochem. J. 366, 423-434

"Enzymatic synthesis of monocyclic beta-lactams", Sleeman, M. C., MacKinnon, C. H., Hewitson, K. S., and Schofield, C. J. (2002) Bioorg. Med. Chem. Lett. 12, 597-599
     

 
   

 

 

 

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